Isoskeletal Schiff base polynuclear coordination clusters: synthetic and theoretical aspects†
نویسندگان
چکیده
This work addresses and enlightens synthetic aspects derived from our effort to systematically construct isoskeletal tetranuclear coordination clusters (CCs) of the general formula [TR2Ln2IJLX)4IJNO3)2IJsolv)2] possessing a specific defected dicubane topology, utilizing various substituted Schiff base organic ligands (H2LX) and Ni /Co and DyIJOTf)3 salts. Our synthetic work is further supported by DFT studies.
منابع مشابه
Cobalt(II/III), nickel(II) and copper(II) coordination clusters employing a monoanionic Schiff base ligand: synthetic, topological and computational mechanistic aspects
http://sro.sussex.ac.uk Loukopoulos, Edward, Berkoff, Benjamin, Griffiths, Kieran, Keeble, Victoria, Dokorou, Vassiliki N, Tsipis, Athanassios C, Escuer, Albert and Kostakis, George E (2015) Cobalt(II/III), nickel(II) and copper(II) coordination clusters employing a monoanionic Schiff base ligand: synthetic, topological and computational mechanistic aspects. CrystEngComm, 17 (35). pp. 6753-6764...
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متن کاملCobalt IJ II / III ) , nickel IJ II ) and copper IJ II ) coordination clusters employing a monoanionic Schiff base ligand : synthetic , topological and computational mechanistic aspects †
CrystEngComm This journal is © The Royal Society of Chemistry 2015 Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK. E-mail: [email protected] b Laboratory of Inorganic and General Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece. E-mail: [email protected] c Departamento de Quimica Inorganica, Universitat de Barc...
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